Synthesis and Microwave Absorption Properties of Sulfur-Free Expanded Graphite/Fe₃O₄ Composites

In this study, sulfur-free expanded graphite (EG) was obtained by using flake graphite as the raw material, and EG/Fe₃O₄ composites with excellent microwave absorption properties were prepared by a facile one-pot co-precipitation method. The structure and properties of as-prepared EG/Fe₃O₄ were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR), X-ray diffraction (XRD), Raman, X-ray photoelectron spectrometry (XPS), thermogravimetric (TG), and vibrating sample magnetometry (VSM) characterizations. The Fe₃O₄ intercalated between the layers of expanded graphite forms a sandwich-like structure which is superparamagnetic and porous. When applied as a microwave absorber, the reflection loss (R_L) of EG/Fe₃O₄ reaches -40.39 dB with a thickness of 3.0 mm (10 wt% loading), and the effective absorption bandwidth (EAB < -10 dB) with R_L exceeding -10 dB is 4.76-17.66 GHz with the absorber thickness of 1.5-4.0 mm. Considering its non-toxicity, easy operation, low cost, suitability for large-scale industrial production, and excellent microwave absorbing performance, EG/Fe₃O₄ is expected to be a promising candidate for industrialized electromagnetic absorbing materials.