Gold Nanohelices: A New Synthesis Route, Characterization, and Plasmonic E-Field Enhancement

Gold nanohelices (AuNHs) are synthesized using surfactant-assisted seed-mediated growth in an aqueous solution. AuNHs with diameters and lengths of 30-150 nm and several micrometers, respectively, are grown in a reaction carried out at 15 °C for 20 h by adding poly(ethylene glycol)(12)tridecyl ether, polyvinylpyrrolidone, and cetyltrimethylammonium bromide as the capping agents in an HAuCl₄(aq) solution. With the addition of gold nanoparticles (AuNPs) in the reaction, the yield of the helical products is considerably increased, which indicates that AuNPs behave as the seeds for AuNH growth. The growth routes of AuNHs in the system are investigated by transmission electron microscopy measurements. Finite-difference time-domain (FDTD) simulations show that total extinction of the AuNH at 660 and 570 nm is dominantly influenced by strong e-field enhancement and the scattering of light incidence. In a practical application, surface-enhanced Raman scattering (SERS) measurements are conducted using AuNHs as the substrates and 4-mercaptobenzoic acid as the probe. A detection limit of 20 ppb is acquired using a micro-Raman spectrometer using a 633 nm He-Ne laser with a power of 3.35 mW which corresponds with the FDTD simulation results and reveals that AuNHs are superior SERS templates with resonance tuning ability in consequence of their unique helical architectures.