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Updated: Dec 15, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Mesogenic dimers composed of bent-core molecules with flexible alkylene spacer
S Umadevi1, B K Sadashiva1, H N Shreenivasa Murthy1
1Raman Research Institute, C. V. Raman Avenue, Sadashivanagar, Bangalore-560 080, India. sadashiv@rri.res.in.
Abstract:
The synthesis and characterization of six symmetrical mesogenic dimers composed of bent-core molecules containing alkylene spacers are reported. The mesophase was characterized by polarizing optical microscopy, differential scanning calorimetry, X-ray diffraction and electric field experiments. The X-ray diffraction studies revealed a columnar structure with an oblique lattice for the mesophase. The electric field experiments indicated a ferroelectric behaviour for the mesophase. On the basis of obtained experimental data, a possible structural model for the mesophase has been proposed.
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