Synthesis, Characterization, and Multifunctional Applications of Cu-Fe and Ni-Fe Nanomaterials

Cu-Fe and Ni-Fe nanomaterials (NMs) were successfully obtained via a coprecipitation route. Phase analysis and the micro- and physiochemical structure studies for the as-synthesized NMs were carried out with advanced techniques such as TEM, SEM, XRD, XPS, BET, DRS, TGA, and FTIR. Particles with size ranging from 25 to 70 nm were displayed by all the characterization techniques. A surface area of ∼4.48 and 36.52m²/g and band gap energies of ∼1.79 and 1.48 eV were calculated for Cu-Fe and Ni-Fe NMs, respectively. Saturation magnetization (Ms) ∼77.95 emu/g (for Cu-Fe) and 27.70 emu/g (for Ni-Fe) revealed superparamagnetism for both the NMs. The presence of ethanol and methanol as sacrificial agents contributed effectively toward electrocatalytic H-evolution as compared to pure NMs. Furthermore, under solar light irradiations, Cu-Fe and Ni-Fe NMs displayed 85 and 91% degradation during a time interval of 50 and 110 min, respectively, for toxic industrial methylene blue (MB) dye. Different operational variables such as the catalyst amount, pH values, various scavengers, reusability, and stability were thoroughly investigated. Moreover, in situ analysis was carried out in order to determine the mechanism for degradation reactions. A detailed study about various applications categorized the synthesized NMs as efficient candidates for toxic industrial waste cleanup and energy production at an industrial level.