Experimental investigations on the dissipation process of supersaturated total dissolved gas: Focus on the adsorption
Youquan Yuan1, Juping Huang1, Zhenhua Wang1
1State Key Laboratory of Hydraulics and Mountain River Engineering, Sichuan University, Chengdu, Sichuan, 610065, China.
Abstract:
Hydropower, which utilizes energy from fast-moving water, can help alleviate the energy crisis and promote economic development. For safety and ecological purposes, dams must discharge periodically. This discharge process, which occurs with the supersaturation of total dissolved gas (TDG), affects the fish and other aquatic organisms living in downstream river areas. Previous studies have shown that the supersaturated TDG dissipation process is closely related to hydraulic properties such as the flow rate, water depth and turbulent kinetic energy. Additionally, the presence of solid walls such as vegetation leaves in water can adsorb dissolved gases in water, thereby promoting the supersaturated TDG dissipation process, and the adsorption effect is closely related to the solid wall material. However, systematic studies on how solid walls in water can quickly absorb dissolved gases from water and rapidly reduce the TDG saturation of water are lacking. Herein, a series of experiments was conducted to study the dissipation process of supersaturated TDG under the action of solid walls in water and to reveal the adsorption effect of solid wall surface properties on dissolved gas. The results showed that the surface roughness and hydrophobicity (contact angle) are the key factors related to the adsorption effect of solid walls on the TDG in water. Generally, the dissipation rate of supersaturated TDG first increased and then decreased with increasing surface roughness. The supersaturated TDG dissipation rate increased monotonically with increasing contact angle. Based on the experimental data, the adsorption coefficient, which represents the adsorption effect of the solid wall for dissolved gas in water, was proposed, and a prediction formula between the adsorption coefficient and the contact angle of the solid wall was established. These results can provide theoretical support for the utilization of the solid wall adsorption effect to mitigate the adverse effects of supersaturated TDG and protect fish.
Related Concept Videos
Theories of Dissolution: Diffusion Layer Model
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
Physical Properties Affecting Solubility
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
Enthalpy of Solution
Factors Affecting Dissolution: Particle Size and Effective Surface Area


