Hierarchical Fe₃ C-Mo₂ C-Carbon Hybrid Electrocatalysts Promoted through a Strong Charge-Transfer Effect

Highly efficient, stable, and low-cost catalysts for electrochemical water splitting play a critical role in promoting energy efficiency in the renewable hydrogen power-related industries. In this study, nonprecious metal carbides composed of Fe₃ C and Mo₂ C supported by carbon nanoplates are prepared and utilized as bifunctional electrocatalysts for overall water splitting. Spatially confined annealing of the polydopamine-coated metal precursors affords a structure containing porous cubes isolated by carbon nanoplates encapsulated with Fe₃ C and Mo₂ C nanoparticles. The hybrid electrocatalyst with a hierarchical structure, large surface area, and abundant exposed active sites benefits from efficient mass transport and more importantly the strong charge-transfer effect between the iron and molybdenum moieties. Under strong alkaline conditions, the optimized Fe₃ C-Mo₂ C hybrid (with a Fe/Mo ratio of 1 : 2) requires a low overpotential of 274 and 301 mV for the electrocatalytic oxygen evolution reaction at current densities of 10 and 100 mA cm^-2 , respectively, accompanied with decent hydrogen evolution activity, thereby demonstrating efficient bifunctional electrocatalytic activity towards overall water splitting.