In Situ Coating of Li₇P₃S₁₁ Electrolyte on CuCo₂S₄/Graphene Nanocomposite as a High-Performance Cathode for...

A cathode material, CuCo₂S₄/graphene@10%Li₇P₃S₁₁, is reported for all-solid-state lithium batteries with high performance. The electrical conductivity of CuCo₂S₄ is improved by compounding with graphene. Meanwhile, Li₇P₃S₁₁ electrolyte is coated on the surface of CuCo₂S₄/graphene nanosheets to build an intimate contact interface between the solid electrolyte and the electrode effectively, facilitating lithium-ion conduction. Benefitting from the balanced and efficient electronic and ionic conductions, all-solid-state lithium batteries using CuCo₂S₄/graphene@10%Li₇P₃S₁₁ composite as cathode materials demonstrate superior cycling stability and rate capabilities, exhibiting an initial discharge specific capacity of 1102.25 mAh g^-1 at 50 mA g^-1 and reversible capacity of 556.41 mAh g^-1 at a high current density of 500 mA g^-1 after 100 cycles. These results demonstrate that the CuCo₂S₄/graphene@10%Li₇P₃S₁₁ nanocomposite is a promising active material for all-solid-state lithium batteries with superior performances.