A Potential Checkmate to Lead: Bismuth in Organometal Halide Perovskites, Structure, Properties, and Applications

The remarkable optoelectronic properties and considerable performance of the organo lead-halide perovskites (PVKs) in various optoelectronic applications grasp tremendous scientific attention. However, the existence of the toxic lead in these compounds is threatening human health and remains a major concern in the way of their commercialization. To address this issue, numerous nontoxic alternatives have been reported. Among these alternatives, bismuth-based PVKs have emerged as a promising substitute because of similar optoelectronic properties and extended environmental stability. This work communicates briefly about the possible lead-alternatives and explores bismuth-based perovskites comprehensively, in terms of their structures, optoelectronic properties, and applications. A brief description of lead-toxification is provided and the possible Pb-alternatives from the periodic table are scrutinized. Then, the classification and crystal structures of various Bi-based perovskites are elaborated on. Detailed optoelectronic properties of Bi-based perovskites are also described and their optoelectronic applications are abridged. The overall photovoltaic applications along with device characteristics (i.e., V _OC, J _SC, fill factor, FF, and power conversion efficiency, PCE), fabrication method, device architecture, and operational stability are also summarized. Finally, a conclusion is drawn where a brief outlook highlights the challenges that hamper the future progress of Bi-based optoelectronic devices and suggestions for future directions are provided.