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Lattice Centering and Coordination Number02:33

Lattice Centering and Coordination Number

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The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
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Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Synthesis of atomically precise single-crystalline Ru2-based coordination polymers.

Wen-Yang Gao1, Gerard Pierre Van Trieste Iii, David C Powers

  • 1Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX, 77843, USA. powers@chem.tamu.edu.

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|July 18, 2020
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Summary

Synthesizing single-crystalline metal-organic frameworks (MOFs) with inert metal nodes is challenging. This study introduces a novel metallopolymerization method using ruthenium (Ru2) to create precise, crystalline MOF materials for catalysis.

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Area of Science:

  • Materials Science
  • Coordination Chemistry
  • Catalysis

Background:

  • Developing single-crystalline metal-organic frameworks (MOFs) with kinetically inert metal centers and basic ligands presents significant synthetic challenges.
  • The scarcity of such methods limits the exploration of novel heterogeneous catalysts with tunable properties.

Purpose of the Study:

  • To develop a new method for synthesizing single-crystalline MOFs incorporating kinetically inert metal nodes.
  • To enable systematic variation of MOF structures and compositions for potential catalytic applications.

Main Methods:

  • Utilizing kinetically inert Ru2 metallomonomers for metallopolymerization.
  • Employing labile silver-nitrogen (Ag-N) bonds to facilitate framework assembly.
  • Achieving atomically precise single-crystalline coordination polymer synthesis.

Main Results:

  • Successfully synthesized a family of Ru2-based coordination polymers.
  • Demonstrated control over network topology and the primary coordination sphere of the metal nodes.
  • Created atomically precise, single-crystalline MOF materials.

Conclusions:

  • Metallopolymerization via labile Ag-N bonds offers a viable route to inert metal-based MOFs.
  • This approach expands the toolkit for designing and synthesizing advanced heterogeneous catalysts.
  • The synthesized materials hold promise for diverse catalytic applications.