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Related Concept Videos

Cationic Chain-Growth Polymerization: Mechanism00:57

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The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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Formation of liquid core-polymer shell microcapsules.

Huai Nyin Yow1, Alexander F Routh1

  • 1Department of Chemical Engineering and BP Institute, University of Cambridge, Madingley Road, Cambridge, CB3 0EZ. afr10@cam.ac.uk.

Soft Matter
|July 19, 2020
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Summary
This summary is machine-generated.

This review covers various methods for creating polymer shell microcapsules with liquid cores, essential for industries like food and printing. It details techniques such as colloidosome formation and layer-by-layer deposition, outlining their strengths.

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Area of Science:

  • Materials Science
  • Chemical Engineering
  • Polymer Science

Background:

  • Polymer shell microcapsules with liquid cores have diverse industrial applications.
  • These applications span sectors including food protection, flavor encapsulation, and inkless printing technologies.

Purpose of the Study:

  • To review and compare various production methods for polymer shell microcapsules.
  • To outline the characteristics and relative strengths of different microencapsulation techniques.

Main Methods:

  • Colloidosome formation
  • Polymer precipitation via phase separation
  • Polycondensation interfacial polymerization
  • Layer-by-layer polyelectrolyte deposition
  • Polymer growth via surface polymerization
  • Copolymer vesicle formation

Main Results:

  • Each method's distinct characteristics are described.
  • The relative advantages and disadvantages of each technique are discussed.

Conclusions:

  • Understanding the strengths of different microencapsulation methods is crucial for industrial application.
  • This review provides a comparative overview to guide the selection of appropriate production techniques.