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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Rational Designed Mixed-Conductive Sulfur Cathodes for All-Solid-State Lithium Batteries.

Jie Yue1, Yonglin Huang2, Sufu Liu1

  • 1Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, United States.

ACS Applied Materials & Interfaces
|July 21, 2020
PubMed
Summary
This summary is machine-generated.

Researchers developed advanced sulfur cathodes for all-solid-state lithium-sulfur batteries (ASSLSBs). This breakthrough enhances energy storage safety and performance by improving conductivity and accommodating volume changes.

Keywords:
batterycompositemixed conductivesolid electrolytesulfur cathode

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • All-solid-state lithium-sulfur batteries (ASSLSBs) offer high energy density and safety.
  • Developing high-performance sulfur cathodes is challenging due to low conductivity and volume changes.

Purpose of the Study:

  • To synthesize sulfur cathodes with mixed electronic and ionic conductivity for ASSLSBs.
  • To improve the electrochemical performance and stability of sulfur cathodes.

Main Methods:

  • Synthesized sulfur cathodes by infiltrating Li3PS4 solid electrolyte and S active material into mesoporous carbon (CMK-3).
  • Utilized the porous structure of CMK-3 to manage volume changes during cycling.

Main Results:

  • Achieved uniform dispersion of amorphous Li3PS7 catholyte in a conductive carbon matrix.
  • Demonstrated high and balanced electronic/ionic conductivities in the cathode composite.
  • Delivered a capacity of 1025 mAh g-1 after 50 cycles at 60 °C (1/8C) in ASSLSBs with Li metal anodes.

Conclusions:

  • High and balanced electronic and ionic conductivities are crucial for high-performance sulfur cathodes in ASSLSBs.
  • The developed cathode composite shows significant potential for advanced energy storage applications.