Postfunctionalization of Porous Organic Polymers Based on Friedel-Crafts Acylation for CO₂ and Hg²⁺ Capture

Melamine-based porous organic polymers (POPs) are promising for gas uptake and water treatment because of their unique and tunable porosity, high nitrogen (N) content, and high Brunauer-Emmett-Teller (BET) surface area (S_BET). However, it is difficult to construct ketone-based POPs by the Friedel-Crafts acylation reaction. Herein, the ketone-based POPs were postfunctionalized with melamine (MA) by the Schiff-based reaction and the rigid triazine rings of MA were embedded in the polymer chains as rigid cross-linkers, resulting in the polymers with high S_BET (555 m²·g^-1) and total pore volume (0.72 cm³·g^-1). Moreover, plentiful imine, amino, and triazine functionalities were inserted in the polymers, providing the polymers with high N content of 41.83 wt %. The resulting polymers were promising for CO₂ capture (145 mg·g^-1; 273 K, 1.0 bar) and Hg²⁺ removal (372 mg·g^-1). This study offers a universal strategy to construct melamine-based POPs from various ketone-functionalized HCPs via a simple postfunctionalization.