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Updated: Dec 14, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
Elongated-Geminiarene: Syntheses, Solid-State Conformational Investigations, and Application in Aromatics/Cyclic
Jia-Rui Wu1, Yan Wang1, Ying-Wei Yang1
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, International Joint Research Laboratory of Nano-Micro Architecture Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun, 130012, P. R. China.
Abstract:
Energy-saving separation and purification of industrially important compounds with similar physical and chemical properties by novel molecular crystalline materials are of great importance and highly desired. Here a newly enlarged version of geminiarene, namely elongated-geminiarene (ElGA), is first designed and synthesized. Taking advantages of both geminiarenes and biphenarenes, ElGA shows great features including scalable synthesis, nanometer-sized cavity, rich blend of conformational features, and excellent solid-state host-guest properties. Significantly, the functional crystalline materials of ElGA are highly effective in the separation of aromatics and cyclic aliphatics, showing a preference for dimethylbenzene over its corresponding hydrogenation products and paving a new avenue for separation science and industry.
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