WO₃/Buckypaper Membranes for Advanced Oxidation Processes

Photocatalytic materials, such as WO₃, TiO₂, and ZnO nanoparticles, are commonly linked onto porous polymer membranes for wastewater treatment, fouling mitigation and permeation enhancement. Buckypapers (BPs) are entanglements of carbon nanotubes, which have been recently proposed as innovative filtration systems thanks to their mechanical, electronic, and thermal properties. In this work, flexible membranes of single wall carbon nanotubes are prepared and characterized as efficient substrates to deposit by chemical vapor deposition thin layers of WO₃ and obtain, in such a way, WO₃/BP composite membranes for application in advanced oxidation processes. The photocatalytic efficiency of WO₃/BP composite membranes is tested against model pollutants in a small continuous flow reactor and compared with the performance of an equivalent homogeneous WO₃-based reactor.