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PolyHIPE foams from pristine graphene: Strong, porous, and electrically conductive materials templated by a 2D
Elizabeth E B Brown1, Steven J Woltornist2, Douglas H Adamson1
1Institute of Materials Science, Polymer Program, University of Connecticut, Storrs, CT 06269, United States; Chemistry Department, University of Connecticut, Storrs, CT 06269, United States.
Abstract:
Graphene is attractive as a functional 2D surfactant for polymerized high internal phase emulsions (polyHIPEs) due to its remarkable mechanical and electrical properties. We have developed polyHIPEs stabilized by pristine, unoxidized graphene via the spontaneous exfoliation of graphite at high-energy aqueous/organic interfaces. The exfoliated graphene self-assembles into a percolating network and incorporates into the polyHIPE cell walls as verified by TEM. The resulting composites showed compressive strengths of 7.0 MPa at densities of 0.22 g/cm3 and conductivities up to 0.36 S/m. Systematically reducing the concentration of monomer in the oil phase by dilution with a porogenic-acting solvent increased the porosity and lowered the density of the polyHIPEs. Characterization of these composites indicated that graphene's high compressive strength and modulus was transferred to the polyHIPEs and provided mechanical reinforcement even at low polymer content. SEM showed that the morphology of the polymer changed with decreasing monomer content while the graphene lined cells retained their shape. Moreover, we show that the polyHIPEs contain a continuous graphene percolating network resulting in electrically conductive materials at low graphene loading.
