Molecularly Imprinted Porous Aromatic Frameworks for Molecular Recognition

Porous aromatic frameworks (PAFs) are an important class of porous materials that are well-known for their ultralarge surface areas and superb stabilities. Basically, PAF solids are constructed from periodically arranged phenyl fragments connected via C-C bonds (generally), which provide vast accessible surfaces that can be modified with functional groups and intrinsic pathways for rapid mass transfer. Molecular imprinting technology (MIT) is an effective method for producing binding sites with a specific geometry and size that complement a template object. This review focuses on the integration of MIT into PAF structures via state-of-the-art coupling chemistry to expand the application of porous materials in the fields of metal ion extraction (including the nuclear element uranium) and selective catalysis. Additionally, a concise outlook on the rational construction of molecularly imprinted porous aromatic frameworks is discussed in terms of developing next-generation porous materials for broader applications.