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Updated: Dec 13, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Molecular-scale cage-confinement pyrolysis route to size-controlled molybdenum carbide nanoparticles for
Meiling Wang1, Yong Zhang2, Mingzhu Cui3
1Institute of New Carbon Materials, Taiyuan University of Technology, Taiyuan, 030024, Shanxi, China; School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore.
Abstract:
Herein, size-controllable molybdenum carbide nanoparticles (Mo2C NPs) encapsulated by N, P-codoped carbon shells which simultaneously wrapping on the surface of carbon nanotube (Mo2C@NPC/CNT) is synthesized through a molecular-scale cage-confinement pyrolysis route. Such confinement achieves a good coating and protection of Mo2C and the effective control over the size of Mo2C NPs ranging from 2.5 to 10 nm facilitates a rational investigation into their electrochemical sensor behavior at nanometer scales. The optimized structure consisting of Mo2C nanoparticles with size of ~5 nm showed an outstanding electrochemical response toward dopamine (DA) and acetaminophen (AC) with detection limits (S/N = 3) of 0.008 μM for AC and 0.01 μM for DA.
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