Linear bulk photovoltaic effect and phenomenological study in multi-phase co-existing ferroelectric system

Ferroelectric systems with multi-phase co-existence are found to exhibit anomalous photovoltaic response. In this work, detailed photovoltaic studies are carried out under 405 nm light illumination on Ba_1-x(Bi_0.5Li_0.5)_xTiO₃ferroelectric oxides having the co-existence of tetragonal and orthorhombic phases. The linear and sinusoidal photocurrent-dependence as a function of light intensity and polarization-direction, respectively elucidate the experimental evidence for linear bulk-photovoltaic effect. Importantly, the temperature-dependent photovoltaic studies display 2-fold enhancement in photovoltage near the ferroelectric transition temperature (T_C). The observed features in photovoltage follow inverse temperature-dependence of the photoconductivity. The linear relationship between the calculated bulk-photovoltaic tensor component and the photocurrent established from the proposed phenomenological model is verified through their composition-dependent studies. These studies provide the desired design parameters to engineer the ferroelectric system for better photovoltaic characteristics suitable for device applications.