Diffusion-layer-free air cathode based on ionic conductive hydrogel for microbial fuel cells

High hydraulic pressure in air-cathode microbial fuel cells (MFCs) can lead to severe cathodic water leakage and power reduction, thereby hindering the practical applications of MFCs. In this study, an alternative air cathode without a diffusion layer was developed using a cross-linked hydrogel, oxidized konjac glucomannan/2-hydroxypropytrimethyl ammonium chloride chitosan (OKH), for ion bridging. The cathode was placed horizontally to avoid hydraulic pressure on its surface. Ion transportation was sustained with a minimal OKH hydrogel loading of 10 mg/cm². A maximum power density of 1.0 ± 0.04 W/m² was achieved, which was only slightly lower than the 1.28 ± 0.02 W/m² of common air cathodes. Moreover, the cost of the OKH hydrogel is only $0.12/m², which can reduce ~85% of the cathode cost without using the advanced polyvinylidene fluoride diffusion layer. Therefore, the development of this new diffusion-layer-free air cathode using conductive ionic hydrogel provides a low-cost strategy for stable MFC operation, thereby demonstrating great potential for practical applications of MFC technology.