Spatial distribution of fine and coarse particulate matter during a southwest monsoon in Peninsular Malaysia

This study aimed to determine the spatial distribution of PM_2.5 and PM₁₀ collected in four regions (North, Central, South and East Coast) of Peninsular Malaysia during the southwest monsoon. Concurrent measurements of PM_2.5 and PM₁₀ were performed using a high volume sampler (HVS) for 24 h (August to September 2018) collecting a total of 104 samples. All samples were then analysed for water soluble inorganic ions (WSII) using ion chromatography, trace metals using inductively coupled plasma-mass spectroscopy (ICP-MS) and polycyclic aromatic hydrocarbon (PAHs) using gas chromatography-mass spectroscopy (GC-MS). The results showed that the highest average PM_2.5 concentration during the sampling campaign was in the North region (33.2 ± 5.3 μg m^-3) while for PM₁₀ the highest was in the Central region (38.6 ± 7.70 μg m^-3). WSII recorded contributions of 22% for PM_2.5 and 20% for PM₁₀ mass, with SO₄^2- the most abundant species with average concentrations of 1.83 ± 0.42 μg m^-3 (PM_2.5) and 2.19 ± 0.27 μg m^-3 (PM₁₀). Using a Positive Matrix Factorization (PMF) model, soil fertilizer (23%) was identified as the major source of PM_2.5 while industrial activity (25%) was identified as the major source of PM₁₀. Overall, the studied metals had hazard quotients (HQ) value of <1 indicating a very low risk of non-carcinogenic elements while the highest excess lifetime cancer risk (ELCR) was recorded for Cr VI in the South region with values of 8.4E-06 (PM_2.5) and 6.6E-05 (PM₁₀). The incremental lifetime cancer risk (ILCR) calculated from the PAH concentrations was within the acceptable range for all regions.