A plasma thermal slag-derived from hazardous waste has a born hydrothermal stability

Hydrothermal instability restricts performances of silica-based catalysts, which have wide applications in both industry and environment. For the first time, plasma-thermal slag was revealed to be a catalyst with a born hydrothermal stability in selective catalytic reduction of nitric oxide. The slag catalyst removed 98.5 % of NO with a high N₂ selectivity (> 95 %) at 200 °C. After a hydrothermal treatment at 900 °C, the activity of the slag only decreased to 84.0 %. According to characterizations of XRD, HTREM, XPS, and EPR, active metals existed in coordination states in the slag at first. Under hydrothermal conditions, these species transformed to short-range single crystals, which were hindered from sintering by surrounded Si-O bands. At the same time, in-situ DRIFT indicated that more Brønsted and Lewis acid sites were formed. Hence, enough active sties were reserved for effective catalytic reduction of nitric oxide. The main result of this work helps us to understand hydrothermal stability of a catalyst. What's more, the high-value-added utilization of plasma-thermal slag is in favor of the development of hazardous-waste treatment.