Can flow-electrode capacitive deionization become a new in-situ soil remediation technology for heavy metal removal?

In this study, we present a novel soil electrochemical remediation technology (called S-FCDI), which is based on flow-electrode capacitive deionization (FCDI), for Cd removal from kaolin while under continuous operation mode. The results demonstrated that Cd can be effectively removed from kaolin with reasonable energy consumption and minimal macroelement loss. The carboxylic (OOH) functional groups on the surface of activated carbon (AC) facilitated the transfer of Cd from kaolin onto carbon surface. A stable acidic environment, which is advantageous for continuous Cd desorption, was achieved as a result of the balance between H⁺ generation and transmembrane migration. Once these net negative charges on the particle were eliminated or reversed, the adsorbed Cd could be released easily and driven in concentrated stream by electrostatic repulsion. Under the optimal operating conditions (i.e., carbon =50 g/L, j = 3.47 A/m², pH_i = 3.2, [NaCl]_a =8.6 mmol/L), more than 80 % Cd was removed from (200 g) kaolin after continuous 19 h operation at a relatively low electricity consumption of 22.7 kW h/kg Cd and a limited Al loss of 0.06 wt‰. These results from this work demonstrated that S-FCDI could be an alternative soil electrochemical remediation technology for heavy metal removal with low soil damage.