Non-Coordinated Phenolate Anions and Their Application in SF6 Activation
Robin F Weitkamp1, Beate Neumann1, Hans-Georg Stammler1
1Centrum für Molekulare Materialien, Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, 33615, Bielefeld, Germany.
Abstract:
The reaction of the strong monophosphazene base with the weakly acidic phenol leads to the formation of a phenol-phenolate anion with a moderately strong hydrogen bond. Application of the more powerful tetraphosphazene base (Schwesinger base) renders the isolation of the corresponding salt with a free phenolate anion possible. This compound represents the first species featuring the free phenolate anion [H5 C6 -O]- . The deprotonation of phenol derivatives with tetraphosphazene bases represents a great way for the clean preparation of salts featuring free phenolate anions and in addition allows the selective syntheses of hydrogen bonded phenol-phenolate salts. This work presents a phosphazenium phenolate salt with a redox potential of -0.72 V and its capability for the selective activation of the chemically inert greenhouse gas SF6 . The performed two-electron reduction of SF6 leads to phosphazenium pentafluorosulfanide ([SF5 ]- ) and fluoride salts.
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