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Updated: Dec 12, 2025

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
A turn-on TADF chemosensor for sulfite with a microsecond-scale luminescence lifetime
Huiyi Yin1, Yingnan Wu, Xiaojun Peng
1State Key Laboratory of Fine Chemicals, Dalian University of Technology, No. 2 Linggong Road, High-tech District, Dalian, 116024, China. songfl@dlut.edu.cn.
Abstract:
A reaction-based luminescence chemosensor was synthesized for sulfite detection based on a fluorescein derivative with thermally activated delayed fluorescence (TADF). The chemosensor exhibited a fluorescence turn-on effect on sulfite with good sensitivity and selectivity. Importantly, utilizing the long luminescence lifetime of the TADF compound, the chemosensor realized photoluminescence lifetime imaging for sulfite in living cells with the luminescence lifetime distribution mainly around 14 μs.
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