Zeolite (In)Stability under Aqueous or Steaming Conditions

Zeolites are among the most environmentally friendly materials produced industrially at the Megaton scale. They find numerous commercial applications, particularly in catalysis, adsorption, and separation. Under ambient conditions aluminosilicate zeolites are stable when exposed to water or water vapor. However, at extreme conditions as high temperature, high water vapor pressure or increased acidity/basicity, their crystalline framework can be destroyed. The stability of the zeolite framework under aqueous conditions also depends on the concentration and character of heteroatoms (other than Al) and the topology of the zeolite. The factors critical for zeolite (in)stability in the presence of water under various conditions are reviewed from the experimental as well as computational sides. Nonreactive and reactive interactions of water with zeolites are addressed. The goal of this review is to provide a comparative overview of all-silica zeolites, aluminosilicates and zeolites with other heteroatoms (Ti, Sn, and Ge) when contacted with water. Due attention is also devoted to the situation when partial zeolite hydrolysis is used beneficially, such as the formation of hierarchical zeolites, synthesis of new zeolites or fine-tuning catalytic or adsorption characteristics of zeolites.