Removal of aniline from wastewater by electro-polymerization with superior energy efficiency

Removal of toxic aniline from wastewater is of great importance in industrial manufacture. Traditional electrochemical methods encounter obstacles such as high energy consumption in mineralization and severe electrode passivation in electro-polymerization. In this paper, we report a practical electro-polymerization method by using Ti/Sb-SnO₂/PbO₂ anode to treat high concentration aniline wastewater. The cyclic voltammetric experiment was conducted and the problem of electrode passivation was solved by increasing the electrode potential. In the experiments of treating aniline wastewater, the produced solid polymer can separate from water rather than sticking to electrode surface. Elemental analysis shows that oxygen is incorporated in the polymer. Experiments were conducted under different conditions, including current density, pH and initial concentration of aniline and Na₂SO₄. The electro-polymerization route accounts for nearly 50% contribution in the removal of chemical oxygen demand (COD). Our electro-polymerization method gives an apparent current efficiency (ACE) of 232.15% and an energy consumption (E_p) of 0.008658 kWh g^-1_COD^-1 when half of COD is removed at a current density of 15 mA cm^-2, pH of 7.0, initial aniline concentration of 1.2 g L^-1 and Na₂SO₄ concentration of 4 g L.^-1.