PDA-cross-linked beta-cyclodextrin: a novel adsorbent for the removal of BPA and cationic dyes
Jianyu Wang1, Guang Cheng1, Jian Lu1
1National Engineering Laboratory for Industrial Wastewater Treatment, East China University of Science and Technology, No. 130 Meilong Road, Shanghai 200237, China
Abstract:
In this study, 4,4'-(hexafluoroisopropene) diphthalic acid (PDA)-CD polymers containing β-cyclodextrin (CD) were synthesized for the adsorption of endocrine disrupting chemicals (EDCs) and dyes. It features great adsorption of bisphenol A (BPA), methylene blue (MB) and neutral red (NR). The maximum adsorption capacities of MB, NR and BPA can reach 113.06, 106.8 and 51.74 mg/g, respectively. The tandem adsorption results revealed that adsorptions of dyes and BPA onto PDA-CD polymer were two independent processes: non-polar BPA entrapment by cyclodextrin cavities while dyes were captured by the carboxyl groups and π-π stacking interactions. The adsorption processes performed well in a wide range of pH (4.0-10.0) and were not affected by fulvic acid (FA) and inorganic ions.
