Targeted Assembly of Ultrathin NiO/MoS₂ Electrodes for Electrocatalytic Hydrogen Evolution in Alkaline Electrolyte

The development of non-noble metal catalysts for hydrogen revolution in alkaline media is highly desirable, but remains a great challenge. Herein, synergetic ultrathin NiO/MoS₂ catalysts were prepared to improve the sluggish water dissociation step for HER in alkaline conditions. With traditional electrode assembly methods, MoS₂:NiO-3:1 exhibited the best catalytic performance; an overpotential of 158 mV was required to achieve a current density of 10 mA/cm². Further, a synergetic ultrathin NiO/MoS₂/nickel foam (NF) electrode was assembled by electrophoretic deposition (EPD) and post-processing reactions. The electrode displayed higher electrocatalytic ability and stability, and an overpotential of only 121 mV was needed to achieve a current density of 10 mA/cm². The improvement was ascribed to the better catalytic environment, rather than a larger active surface area, a higher density of exposed active sites or other factors. DFT calculations indicated that the hybrid NiO/MoS₂ heterostuctured interface is advantageous for the enhanced water dissociation step and the corresponding lower kinetic energy barrier-from 1.53 to 0.81 eV.