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Published on: January 20, 2023
Paris car parking problem for partially oriented discorectangles on a line
Nikolai I Lebovka1,2, Mykhailo O Tatochenko3, Nikolai V Vygornitskii1
1Department of Physical Chemistry of Disperse Minerals, F. D. Ovcharenko Institute of Biocolloidal Chemistry, NAS of Ukraine, Kyiv 03142, Ukraine.
Random sequential adsorption of elongated particles on a line forms ordered stacks and rarefied holes. Particle orientation and aspect ratio significantly impact jamming density and packing structures.
Area of Science:
- Physics
- Materials Science
- Statistical Mechanics
Background:
- The random sequential adsorption (RSA) model is a fundamental concept in statistical physics.
- Understanding particle packing is crucial for materials science and fluid dynamics.
- The
- Paris car parking problem
- serves as a basis for studying constrained particle deposition.
Purpose of the Study:
- To numerically investigate the RSA of elongated particles (discorectangles) on a line.
- To analyze the influence of particle aspect ratio and orientation on packing density and structure.
- To explore the competition between orientational freedom and excluded volume effects.
Main Methods:
- Off-lattice numerical simulation with continuous positional and orientational degrees of freedom.
- Variation of discorectangle aspect ratio (ɛ) from 1 to 100, including the limiting case of widthless sticks (ɛ=∞).
- Restricted particle orientations within a defined angular range (θ∈[-θm;θm]).
Main Results:
- RSA deposition leads to the formation of rarefied holes and dense stacks of particles.
- Kinetics of order parameter and packing density changes were analyzed.
- Partial ordering significantly affected jamming density (φj) and shifted cusps in φj(ɛ) dependencies.
Conclusions:
- The interplay between particle orientation and excluded volume effects governs packing density.
- The aspect ratio of elongated particles critically influences the jamming state.
- The observed structures provide insights into self-assembly processes and dense packing phenomena.
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