Luminescence of Eu (III) complex under near-infrared light excitation for curcumin detection

An intrinsic Eu(III) luminescence phenomenon of Eu(III) complex was found under near-infrared light (NIRL) excitation of xenon lamp, and the maximum excitation wavelength is about twice the excitation wavelength of its Stokes fluorescence. The NIRL excitation fluorescence was mainly originated from second order diffracted light (SODL) excitation. The Eu(III) complex was consist of Eu(III), Gd(III), 2-trifluoroacetylacetone (TTA) and cetyltrimethylammonium bromide (CTAB). Curcumin (Cur) could notably quench the luminescence intensity of the Eu(III) complex. Based on this, a sensitive method for Cur detection was developed. Under optimum conditions, the decrease extent in the fluorescence intensity at 611 nm exhibited a good linear relationship with the Cur concentration in the range of 2.0 × 10^-9 mol/L - 6.0 × 10^-8 mol/L under 746 nm excitation, the limit of detection (LOD, S/N = 3) was 5.2 × 10^-10 mol/L. While, the linear relationship and the LOD of Stokes fluorescence method (λ_ex/λ_em = 360/611 nm) were found to be 1.0 × 10^-8 mol/L - 6.0 × 10^-8 mol/L and 2.6 × 10^-9 mol/L, respectively. The former method is superior to the latter one in Cur detection. Both two methods were successfully applied to determine Cur in real samples. The luminescence mechanism of Eu(III) complex under the NIRL excitation and the quenching mechanism of Cur on the Eu(III) fluorescence was also investigated.