Large Interlayer Spacing of Few-Layered Cobalt-Tin-Based Sulfide Providing Superior Sodium Storage

Mixed transition metal sulfides (MTMSs) have been regarded as a potential anode material for sodium-ion batteries (SIBs) due to their high reversible specific capacity. Herein, nanoflower-like few-layered cobalt-tin-based sulfide (F-CoSnS) with a large interlayer spacing is synthesized via a facile route for superior sodium storage. The growth mechanism of this unique F-CoSnS is systematically studied. Such distinctive nanostructured engineering synergistically combines a broad interlayer spacing (∼ 0.85 nm), the functionalities of few (2-3) layers, and the introduction of heterogeneous metal atoms, reducing the ion diffusion energy barrier for high-efficiency intercalation/deintercalation of Na⁺ ions, as revealed by density functional theory (DFT) calculations. With further incorporation of a three-dimensional (3D) conductive network, the F-CoSnS@C electrode shows a large sodium storage capacity (493.4 mAh g^-1 at 50 mA g^-1), remarkable rate capability (316.1 mAh g^-1 at 1600 mA g^-1), and superior cycling stability (450 mAh g^-1 at 50 mA g^-1 with 91.2% capacity retention, 0.044% fading rate per cycle, and approximately 100% Coulombic efficiency after 200 cycles). This work demonstrates that the few-layered ternary MTMSs are highly applicable for the development of advanced SIB anode materials with high performance.