Printable 3D Carbon Nanofiber Networks with Embedded Metal Nanocatalysts

Carbon nanofiber (CNF) nanocatalyst hybrids hold great promise in fields such as energy storage, synthetic chemistry, and sensors. Current strategies to generate such hybrids are laborious and utterly incompatible with miniaturization and large-scale production. Instead, this work demonstrates that Ni nanoparticles embedded in three-dimensional (3D) CNFs of any shape and design can be easily prepared using electrospinning, followed by laser carbonization under ambient conditions. Specifically, a solution of nickel acetylacetonate /polyimide is electrospun and subsequently a design is printed via CO₂ laser (Ni-laser-induced carbon nanofiber (LCNFs)). This creates uniformly distributed small Ni nanoparticles (∼8 nm) very tightly adhered to the CNF network. Morphological and performance characteristics can be directly influenced by metal content and lasing power and hence adapted for the desired application. Here, Ni-LCNFs are optimized for nonenzymatic electrochemical sensing of glucose with great sensitivity of 2092 μA mM^-1 cm^-2 and a detection limit down to 0.3 μM. Its selectivity for glucose vs interfering species (ascorbic and uric acid) is essentially governed by the Ni content. Most importantly, this strategy can be adapted to a whole range of metal precursors and hence provide opportunities for such 3D CNF-nanocatalyst hybrids in point-of-care applications where high-performance but also sustainable and low-cost fabrications are of utmost importance.