Putting Ink into Polyion Micelles: Full-Color Anticounterfeiting with Water/Organic Solvent Dual Resistance

Anticounterfeiting paintings are usually with limited colors and easy blurring and need to be dispersed in an environmentally unfriendly organic solvent. We report a set of water-based polyion micellar inks to solve all these problems. Upon complexation of reversible coordination polymers formed with rare earth metal ions Eu³⁺ and Tb³⁺ and the aggregation-induced emission ligand tetraphenylethylene-L₂EO₄ with oppositely charged block polyelectrolyte P2MVP₂₉-b-PEO₂₀₅, we are able to generate polyion micelles displaying three elementary emission colors of red (R) (Φ_Eu = 24%), green (G) (Φ_Tb = 7%), and blue (B) (Φ_TPE = 9%). Full-spectrum emission and white light emission (0.34, 0.34) become possible by simply mixing the R, G, and B micelles at the desired fraction. Strikingly, the micellar inks remain stable even after soaking in water or organic solvents (ethyl acetate, ethanol, etc.) for 24 h. We envision that polyion micelles would open a new paradigm in the field of anticounterfeiting.