Waste Containment Ponds Are a Major Source of Secondary Organic Aerosol Precursors from Oil Sands Operations

The surface mining and bitumen extraction of oil sands (OS) generates over one million barrels of heavy oil each day in the Alberta Oil Sands Region of Canada. Recent observations suggest that emissions from OS development contribute to secondary organic aerosol (SOA) formation, but the chemical composition, mass fluxes, and sources of those emissions are poorly delineated. Here, we simulated OS extraction and used comprehensive two-dimensional gas chromatography to quantify and characterize direct air emissions, bitumen froth, residual wastewater, and tailings components, ultimately enabling fate modeling of over 1500 chromatographic features simultaneously. During the non-ice cover season, tailings ponds emissions contributed 15 000-72 000 metric tonnes of hydrocarbon SOA precursors, translating to 3000-13 000 tonnes of SOA, whereas direct emissions during the extraction process itself were notably smaller (960 ± 500 tonnes SOA yr^-1). These results suggest that tailings pond waste management practices should be targeted to reduce environmental emissions.