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Updated: Dec 11, 2025

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Published on: August 1, 2018
N-Acyl Dibenzazepine Chemistry as Versatile Approach for Photoreversible Thiol-Ene Networks
Semira Bener1, Cansu Aydogan1, Yusuf Yagci1,2
1Istanbul Technical University, Faculty of Science and Letters, Department of Chemistry, Maslak, Istanbul, 34469, Turkey.
Abstract:
It is herein reported that a facile application of N-acyl dibenzazepine (ADBA) photochemistry for preparing photoreversible ADBA based thiol-ene networks. Crosslinking of the ADBA thiol-ene networks is successfully achieved by UV induced dimerization of ADBA groups at wavelengths above 300 nm while a subsequent deep UV exposure (λ = 250 nm) results in a well-defined cleavage of the crosslinks. The photochemical bonding and cleavage of the process has been determined and studied in detail by spectroscopic measurements.
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