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The Periodic Table03:25

The Periodic Table

100.4K
As early chemists discovered more elements, they realized that various elements could be grouped by their similar chemical behaviors. One such grouping includes lithium (Li), sodium (Na), and potassium (K). All of these elements are shiny, conduct heat and electricity well, and have similar chemical properties. A second grouping includes calcium (Ca), strontium (Sr), and barium (Ba), which also are shiny, good conductors of heat and electricity, and have chemical properties in common. However,...
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Atomic Radii and Effective Nuclear Charge03:08

Atomic Radii and Effective Nuclear Charge

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The elements in groups of the periodic table exhibit similar chemical behavior. This similarity occurs because the members of a group have the same number and distribution of electrons in their valence shells.
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Periodic Classification of the Elements04:00

Periodic Classification of the Elements

57.3K
The periodic table arranges atoms based on increasing atomic number so that elements with the same chemical properties recur periodically. When their electron configurations are added to the table, a periodic recurrence of similar electron configurations in the outer shells of these elements is observed. Because they are in the outer shells of an atom, valence electrons play the most important role in chemical reactions. The outer electrons have the highest energy of the electrons in an atom...
57.3K
The Bohr Model02:18

The Bohr Model

79.2K
Following the work of Ernest Rutherford and his colleagues in the early twentieth century, the picture of atoms consisting of tiny dense nuclei surrounded by lighter and even tinier electrons continually moving about the nucleus was well established. This picture was called the planetary model since it pictured the atom as a miniature “solar system” with the electrons orbiting the nucleus like planets orbiting the sun. The simplest atom is hydrogen, consisting of a single proton as the...
79.2K
Space-Time Curvature and the General Theory of Relativity01:17

Space-Time Curvature and the General Theory of Relativity

3.8K
In 1905, Albert Einstein published his special theory of relativity. According to this theory, no matter in the universe can attain a speed greater than the speed of light in a vacuum, which thus serves as the speed limit of the universe.
This has been verified in many experiments. However, space and time are no longer absolute. Two observers moving relative to one another do not agree on the length of objects or the passage of time. The mechanics of objects based on Newton's laws of...
3.8K
The de Broglie Wavelength02:32

The de Broglie Wavelength

32.4K
In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
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Related Experiment Video

Updated: Dec 11, 2025

Preparing an Isotopically Pure 229Th Ion Beam for Studies of 229mTh
10:42

Preparing an Isotopically Pure 229Th Ion Beam for Studies of 229mTh

Published on: May 3, 2019

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Relativity and the periodic table.

N C Pyper1

  • 1Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.

Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences
|August 20, 2020
PubMed
Summary
This summary is machine-generated.

Relativistic quantum mechanics is essential for understanding heavy elements where electron speeds approach light speed. It explains how relativity alters electron behavior, impacting periodic trends and chemical properties of heavier elements.

Keywords:
periodic tablequantum mechanicsrelativity

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Area of Science:

  • * Inorganic Chemistry
  • * Quantum Mechanics
  • * Physical Chemistry

Background:

  • * Non-relativistic quantum mechanics successfully explains chemical behavior for elements in the fifth and earlier rows of the periodic table.
  • * For heavy elements (sixth row and higher), non-relativistic quantum mechanics fails to predict observed chemical properties.
  • * Relativistic effects become significant as electron velocities approach the speed of light in heavy elements.

Purpose of the Study:

  • * To explain how relativistic quantum mechanics modifies valence electron behavior in heavy elements.
  • * To elucidate the direct and indirect relativistic effects on electron orbitals and their impact on chemical trends.
  • * To provide a non-mathematical description of these relativistic phenomena.

Main Methods:

  • * Theoretical analysis of relativistic quantum mechanics.
  • * Examination of relativistic effects on electron orbital energies and shapes.
  • * Comparison of predicted chemical behaviors with experimental observations for heavy elements.

Main Results:

  • * Direct relativistic effects contract low angular momentum orbitals, increasing binding energy.
  • * Indirect relativistic effects enhance screening of high angular momentum orbitals due to core orbital contraction.
  • * These effects alter periodic trends, making heavy alkali/alkaline earth metals less reactive and heavier coinage metals more chemically active.
  • * Relativistic effects influence the distinct chemistries of sixth-row transition elements, lanthanides, and actinides.
  • * For 7p elements, relativistic effects significantly inhibit covalent bond formation.

Conclusions:

  • * Relativistic quantum mechanics is crucial for accurately describing the chemistry of heavy elements.
  • * Relativistic effects systematically alter chemical properties and trends down the periodic table.
  • * Understanding these effects is key to predicting and explaining the behavior of elements across different rows.