Charge transfer complexes: Emerging and promising colorimetric real-time chemosensors for hazardous materials

After introducing the concept of charge transfer (CT) complex formation by Mulliken and the discovery of crystalline picrate (association of picric acid and aromatic hydrocarbons) by Fritzsches, a large interest has been drawn in this field. CT complexes have been explored and exploited for different applications for several decades. The research has been aimed mostly for discovering and characterizing new CT materials and exploring applications mainly in the field of optoelectronic properties, antimicrobial activities and DNA/protein binding properties for the last six years. However, nowadays, CT complexes are exploited for their photocatalytic activities and designing chemosensors for the colorimetric real-time detection of hazardous materials like nitro explosives, anions and toxic heavy metal ions in an aqueous medium. This review sheds light on updates on CT complexes, their types, synthesis and applications. The brief discussion on the emergence of CT complexes as highly potential chemosensors along with the explanation of sensing mechanism through article summarization is the centerpiece of this review. The final outcomes are discussed and concluded.