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Updated: Dec 11, 2025

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Structure-directing sulfur...metal noncovalent semicoordination bonding

Ivan V Ananyev1, Nadezhda A Bokach2, Vadim Yu Kukushkin2

  • 1Laboratory of X-ray Structural Studies, Institute of Organoelement Compounds (INEOS) of RAS, Vavilova Str., 28, Moscow, 119991, Russian Federation.

Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials
|August 25, 2020
PubMed
Summary

This study reveals that metal-sulfur interactions in late transition metal complexes are primarily semicoordination bonds. These interactions, analyzed via CSD and DFT, play a key role in stabilizing complex conformations.

Keywords:
CSDchalcogen bondcharge transfernoncovalent interactionsreal-space methodssemicoordination

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