Study of Interactions between Interfacial Nanobubbles and Probes of Different Hydrophobicities

In this study, hydrophilic, medium hydrophobic, and strong hydrophobic probes are obtained via treatment with plasma and octadecyl trichlorosilane. The interaction between the probes and interfacial nanobubbles (INBs) is examined using atomic force microscopy. The results show that a hydrophilic probe can scan the true shape of the INBs, and the distance between the first inflection point and the zero point of the approach force curve is equal to the vertical height of the nanobubble. The medium hydrophobic probe caused severe deformation of INB morphologies in the horizontal direction during scanning; nevertheless, the complete shape of the INB is obtained using this probe by lowering the scanning parameters. However, the characteristic of the approach force curve proves that the size of the nanobubbles is underestimated. The strong hydrophobic probe deforms INB morphologies severely, whose size cannot be obtained. The maximum attractive force in the approach force curve and the adhesive force in the retract force curve obtained using the strong hydrophobic probe are approximately 6 and 12 nN, respectively, which are both higher than those of the hydrophilic and medium hydrophobic probes. It is reasoned that the liquid film is maintained between the hydrophilic probe and the INBs, the medium hydrophobic probe pierces the INBs slightly, while the strong hydrophobic probe punctures the liquid film and demonstrates a pinning effect.