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Updated: Dec 10, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Electron-Deficient Conjugated Materials via p-π* Conjugation with Boron: Extending Monomers to Oligomers,
Xiaodong Yin1,2, Jun Liu3, Frieder Jäkle1
1Department of Chemistry, Rutgers University-Newark, 73 Warren Street, Newark, NJ, 07102, USA.
Abstract:
The extension of conjugated organoboranes from monomeric species to oligomers, macrocycles, and polymers offers access to a plethora of fascinating new materials. The p-π* conjugation between empty orbitals on boron and the conjugated linkers not only affects the electronic structure and optical properties, but also enables mutual interactions between electron-deficient boron centers. The unique properties of these electron-deficient π-conjugated systems are exploited in highly luminescent materials, organic optoelectronic devices, and sensing applications.
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