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Updated: Dec 10, 2025

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
Published on: April 28, 2023
A new Collinear Apparatus for Laser Spectroscopy and Applied Science (COALA)
K König1, J Krämer1, C Geppert2
1Institut für Kernphysik, Technische Universität Darmstadt, 64289 Darmstadt, Germany.
Abstract:
We present a new collinear laser spectroscopy setup that has been designed to overcome systematic uncertainty limits arising from high-voltage and frequency measurements, beam superposition, and collisions with residual gas that are present in other installations utilizing this technique. The applied methods and experimental realizations are described, including an active stabilization of the ion-source potential, new types of ion sources that have not been used for collinear laser spectroscopy so far, dedicated installations for pump-and-probe measurements, and a versatile laser system referenced to a frequency comb. The advanced setup enables us to routinely determine transition frequencies, which was so far demonstrated only for a few cases and with lower accuracy at other facilities. It has also been designed to perform accurate high-voltage measurements for metrological applications. Demonstration and performance measurements were carried out with Ca+ and In+ ions.
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