Self-Powered Potentiometric Sensor Transduction to a Capacitive Electronic Component for Later Readout

Potentiometric sensors operate as galvanic cells where the voltage is spontaneously generated as a function of the sample composition. We show here that energy can be harvested, stored during the sensing process without external power, and physically isolated from the sensor circuit for later readout. This is accomplished by placing an electronic capacitor as a portable transduction component between the indicator and the reference electrode at the point where one would ordinarily connect the high-input-impedance voltmeter. The voltage across this isolated capacitor indicates the originally measured ion activity and can be read out conveniently, for example, using a simple handheld multimeter. The capacitor is shown to maintain the transferred charge for hours after its complete disconnection from the sensor. The concept is demonstrated to detect the physiological concentrations of K⁺ in artificial sweat samples. The methodology provides a readout principle that could become very useful in portable form factors and opens possibilities for potentiometric detection in point-of-care applications and inexpensive sensing devices where an external power source is not desired.