Preparation and Magnetic Properties of CoFe₂O₄ Oriented Fiber Arrays by Electrospinning

The morphology of magnetic materials has a great influence on the properties, which is attributed to the magnetic anisotropy of the materials. Therefore, it is worth studying the fabrication of the aligned fiber and the change of its domain distribution. Nanoparticles and nanofibers were prepared by the hydrothermal and electrospinning methods, respectively. At the same time, the arranged nanofibers were collected by the drum collecting device. After the same annealing at 700 °C, it was found that the diameter of fibers collected by different collecting drums is similar. By studying the hysteresis loops of nanoarrays, it was found that they had strong anisotropy. The easy axis was parallel to the long axis, the Hc and Mr of the easy axis and the hard axis were 1330.5 Oe, 32.39 Am²/kg, and 857.2 Oe, 24.8 Am²/kg, respectively. Due to the anisotropy of the shape and the interaction between the particles, the Hc could not be enhanced. Therefore, the Ms and Hc of the nanoparticles were 80.23 Am²/kg and 979.3 Oe, respectively. The hysteresis loop and the change of magnetic moment during the demagnetization of the CoFe₂O₄ nanofiber array were simulated via micromagnetic software. The simulated Hc was 1480 Oe, which was similar to the experimental value.