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Updated: Dec 10, 2025

Fabrication of Three-Dimensional Graphene-Based Polyhedrons via Origami-Like Self-Folding
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Truncated Face-Rotating Polyhedra Constructed from Pentagonal Pentaphenylpyrrole through Graph Theory
Hang Qu1, Zheyu Huang1, Xue Dong1
1State Key Laboratory of Physical Chemistry of Solid Surfaces, Key Laboratory of Chemical Biology of Fujian Province, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P.R. China.
Abstract:
Discovering novel families of molecular polyhedra through graph theory has attracted increasing interest. Nevertheless, the design principles of molecular polyhedra based on graph theory remain elusive, especially for those containing five-node units. Herein, we construct a series of chiral truncated face-rotating polyhedra (T-FRP) from pentagonal pentaphenylpyrrole (PPP) derivatives and chiral diamines. Graph theory is used to elucidate the geometry of these novel T-FRP, which represent a new family of molecular polyhedra. The phenyl flipping of PPP faces in these T-FRP is significantly restricted, thus making T-FRP chiral and strongly emissive in solution. In addition, T-FRP also generate circularly polarized luminescence. This study provides new insights into the rational design of novel molecular polyhedra through graph theory.
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