A sensitive pyrimethanil sensor based on porous NiCo₂S₄/graphitized carbon nanofiber film

With the extensive use of pesticides, the problem of pesticide residues has become people's concern. In this work, NiCo₂S₄ nanoneedle arrays grown on an electrospun graphitized carbon nanofiber film (NiCo₂S₄/GCNF) is successfully prepared by a simple two-step hydrothermal method, and further applied to detection of fungicide pyrimethanil (PMT). NiCo₂S₄ arrays exhibit a unique core-shell structure with rough surface, providing abundant electrochemically active sites exposed to the electrolyte. The NiCo₂S₄/GCNF modified electrode displays excellent electrocatalytic activity, and the electrode surface is controlled both by diffusion and adsorption processes. When applied to PMT determination, NiCo₂S₄/GCNF sensor displays wide linear range from 0.06 to 800 μM with low detection limit (20 nM). Furthermore, the as-proposed sensor also displays other outstanding advantages, including simple preparation, low cost, perfect reproducibility and good application in practical samples. Such attracting analytical properties could be attributed to high electrocatalytic activity of NiCo₂S₄ and superior electrical conductivity of GCNF frameworks. In addition, the detailed oxidation mechanism of PMT at NiCo₂S₄/GCNF electrode was also studied. The results indicate that NiCo₂S₄/GCNF is a promising platform for PMT sensors.