Anchoring SnS₂ on TiC/C Backbone to Promote Sodium Ion Storage by Phosphate Ion Doping

Tin disulfide (SnS₂ ) shows promising properties toward sodium ion storage with high capacity, but its cycle life and high rate capability are still undermined as a result of poor reaction kinetics and unstable structure. In this work, phosphate ion (PO₄ ^3- )-doped SnS₂ (P-SnS₂ ) nanoflake arrays on conductive TiC/C backbone are reported to form high-quality P-SnS₂ @TiC/C arrays via a hydrothermal-chemical vapor deposition method. By virtue of the synergistic effect between PO₄ ^3- doping and conductive network of TiC/C arrays, enhanced electronic conductivity and enlarged interlayer spacing are realized in the designed P-SnS₂ @TiC/C arrays. Moreover, the introduced PO₄ ^3- can result in favorable intercalation/deintercalation of Na⁺ and accelerate electrochemical reaction kinetics. Notably, lower bandgap and enhanced electronic conductivity owing to the introduction of PO₄ ^3- are demonstrated by density function theory calculations and UV-visible absorption spectra. In view of these positive factors above, the P-SnS₂ @TiC/C electrode delivers a high capacity of 1293.5 mAh g^-1 at 0.1 A g^-1 and exhibits good rate capability (476.7 mAh g^-1 at 5 A g^-1 ), much better than the SnS₂ @TiC/C counterpart. This work may trigger new enthusiasm on construction of advanced metal sulfide electrodes for application in rechargeable alkali ion batteries.