A Synthetic Approach to β-Functionalized Naphtho[2,3]porphyrins
Siddhartha Kumar1, Whitney A Webre1, Courtney Stewart1
1Department of Chemistry, University of North Texas, 1155 Union Circle, #305070, Denton, Texas 76203, United States.
Abstract:
A concise synthetic method has been developed to access functionalized naphtho[2,3]porphyrins through combining two sequence reactions involving a Heck-electrocyclization-aromatization sequence and a Wittig-Knovenegal sequence. Using this method, mononaphtho[2,3]porphyrin (NP-1), opp-dinaphtho[2,3]porphyrin (NP-2), and push-pull naphtho[2,3]porphyrin (NP-3) have been prepared. These naphtho[2,3]porphyrins displayed interesting optical and electrochemical properties. Excellent efficiencies of singlet oxygen generation were obtained for these naphtho[2,3]porphyrins.
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