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Updated: Dec 9, 2025

Rapid Nanoprobe Signal Enhancement by In Situ Gold Nanoparticle Synthesis
Published on: March 7, 2018
Plasmon expedited response time and enhanced response in gold nanoparticles-decorated zinc oxide nanowire-based
Do Wan Kim1, Ki Hong Park2, Seung-Hoon Lee3
1Division of Physics and Semiconductor Science, Dongguk University, Seoul 04620, Republic of Korea.
Abstract:
A highly sensitive and rapidly responsive nitrogen dioxide (NO2) gas sensor based on gold (Au) nanoparticles (NPs)-decorated zinc oxide (ZnO) nanowires (NWs) is presented. The Au NPs decoration was conducted onto ZnO NWs with and without a (3-aminopropyl)triethoxysilane (APTES) layer on their surface by using the electrostatic force. The samples without the APTES layer exhibited high NO2 gas sensitivity (i.e. expedited response time and enhanced gas response) due to localized surface plasmon resonance (LSPR) of the Au NPs; in particular, the NO2 gas response and the response time were increased by three times and shortened by 86%, respectively, compared with the undecorated ZnO NWs. The presence of the APTES layer improved the Au NPs attachment, but hindering the gas adsorption on the ZnO NWs surface, as proven by the observed photocurrent and gas response. Our findings imply that the response time of semiconductor gas sensors can be remarkably expedited by the LSPR effect, which is useful for developing practical gas sensors.
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