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Highly sensitive detection of cobalt through fluorescence changes in β-cyclodextrin-bimane complexes
Apurba Pramanik1, Sara Amer1, Flavio Grynszpan1
1Department of Chemical Sciences, Ariel University, 65 Ramat HaGolan Street, Ariel, Israel. mindyl@ariel.ac.il flaviog@ariel.ac.il.
Abstract:
A supramolecular complex of syn-(methyl,methyl)bimane (1) and β-cyclodextrin demonstrates a sensitive (limit of detection = 0.60 nM) and selective fluorescence turn-off response in the presence of cobalt in aqueous media, with calibration curves enabling quantitation in solution and using filter papers on which bimane and cyclodextrin were adsorbed. 1H NMR spectroscopy provides insight into interactions underlying the sensor performance.
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