Green and Efficient Inkjet Printing of Cotton Fabrics Using Reactive Dye@Copolymer Nanospheres

Digital inkjet printing of textiles possesses great advantages like high efficiency and flexible production, but the challenges like the risk of causing serious environmental problems due to the large usage of dyes and chemicals still remain a matter of concern. In response to this problem, herein, a novel kind of reactive dye@copolymer nanosphere was prepared through the adsorption of C. I. Reactive Red 218 dyes (RR218) onto cationic poly(styrene-butyl acrylate-vinylbenzyl trimethylammonium chloride) (PSBV) nanospheres and applied in inkjet printing on woven cotton fabric. Results show that the prepared RR218@PSBV nanospheres possessed homogeneous size and good stability for ink preparation. In comparison with the original RR218 solution, the color depth of RR218@PSBV-printed fabric increased by 1.4 times and the dye residues in the printing effluent were reduced by about 45%. Meanwhile, the consumptions of sodium carbonate and urea in conventional inkjet printing were reduced by about 3.3 and 22.8 mg/cm², respectively, and the printing process was simplified with 30% energy saving. Furthermore, the mechanism of the color enhancement by nanospheres was revealed by the calculation of absorption and scattering coefficients based on the Kubelka-Munk function. This work provides a potential application of dye@polymer nanospheres to promote the optimization of the textile inkjet printing technique and alleviates the environmental impact of conventional textile coloration.